WSS Training

I found an excellent source text for configuration of Windows SharePoint Services on TechNet:
http://technet.microsoft.com/en-us/library/cc287736(TechNet.10).aspx

More resources:
http://msdn.microsoft.com/en-us/sharepoint/default.aspx
http://msdn.microsoft.com/en-us/sharepoint/aa905692.aspx - screencasts offer an excellent run through of the topics.